Set the BIOS option for the onboard to "UMA."
On the
wiki article for hybrid graphics they say its supported under Vista and XP as well, but they list the supported chipsets: "Hybrid CrossFire X is only available on 790GX, 780G, 760G, 785G, and 880G and 890GX chipsets."
Assuming these criteria are met, and as long as your chipset and Catalyst drivers are recent, it should work. Check out the catalyst control panel to see if theres anything that needs to be enabled there.
EDIT: I'm finding some stuff saying that hybrid crossfire is only supported on the low end cards like the 3470.... Maybe thats why you are having trouble.